Salinity / Electrical Conductivity (EC)

Electrical conductivity (EC) is the most common measure of soil salinity and is indicative of the ability of an aqueous solution to carry an electric current.  Soil salinity refers to dissolved salts such as sodium chloride, calcium chloride and magnesium chloride. The salts may not only be chlorides but carbonates as well. Fertilizers such as nitrates do not have strong conductivities therefore the EC measured in a soil is primarily attributed to sodium.

Many nutrients are salts—a source of salinity. Nutrient accumulation, poor drainage, salt water intrusion in coastal areas and saline irrigation water can lead to the unwanted buildup of salinity in soil. High EC can affect moisture readings and create errors with capacitance-based (time-of charge and frequency) moisture sensors.

Salt (or specifically the dissolved ions in solution) is the primary component of the soil matrix that conducts electricity. While EC is highly dependent on the level of soil salinity, it will also rise and fall with soil moisture.

The effect of EC on the moisture available to a plant’s roots is great. The buildup of salinity in the soil is typically not beneficial to crops, grasses or the microbial community in the soil. Soil salinity also affects the soil hydrology. Plant diseases and pathogens, reduced crop yields or even crop failures may occur from excessive soil salinity, therefore the proper monitoring of soil salinity will help ensure the health of crops.

Soil EC can change dramatically with water content and can be affected by the quality of the irrigation water, fertilization, drainage, and other natural processes. Compaction, clay content and organic matter, can influence moisture holding trends over time, also affecting EC capacities in soil.

Bulk EC Versus Pore Water EC

The EC in soil is more complex than it is in a water sample and can be difficult and confusing to interpret. The bulk soil electrical conductivity (σb) is the EC of the undisturbed soil/water/air matrix and is the parameter measured by soil sensors. It is important not to confuse the bulk EC with the soil pore water EC (σp). Soil pore water EC is the electrical conductivity of the water in the pore spaces of the soil. Because the pore water EC may be difficult to directly measure, a soil slurry can be prepared by taking one part dry soil and two parts distilled water and measuring the EC of the water extract from the slurry. The EC of the extract (ECe or σe) is the parameter traditionally found in soil science or agriculture literature because is relativity easy to measure and provides an “apples to apples” comparison of soil salinity conditions.

Bulk EC and EC Pathways in Soil

Soil is a matrix that is basically composed of solid material, water in the pore spaces and air. In-situ soil sensors (soil sensors in the ground) measure the bulk electrical conductivity (σb) which is the electrical conductivity of the soil/water/air matrix combined.

The image above shows the three pathways the electrical conductivity can propagate in soil. The bulk density, the porosity, the tortuosity, the water content, and the dissolved ion concentration working in concert with the different pathways, dramatically influences the bulk electrical conductivity of a soil.

Pathway 1 is the electrical pathway that goes from water to the soil and back through the water again. The electrical conductivity contribution of pathway 1 is a function of the conductivity of the water and soil. As water increases, the electrical conduit of pathway 1 increases which may increase the electrical conductivity of the soil as a whole.

Pathway 2 is the pathway that is attributed to the electrical conductivity of the just the water in the soil pores. Increasing the dissolved salts will increase the conductivity of pathway 2; however, like pathway 1, increases in the soil water content will increase the size of the pathway thus increasing the overall bulk electrical conductivity. That is to say, that there are two factors influencing the electrical conductivity of pathway 2, namely the dissolved salt concentration and the size of the pathway attributed to the amount of water in the soil.

Pathway 3 is the electrical conductivity of the soil particles. Like the other pathways, the contribution of pathway 3 is influenced by a number of factors that include bulk density, soil type, oxidation/reduction reactions and translocation of ions.

The bulk EC measurements provided by soil sensors is the electrical conductivity of the dynamic soil matrix as a whole, which is the sum of the electrical conductivities from all of the different pathways. No in-situ soil sensor can directly distinguish the difference between the different pathways nor can any conventional in-situ soil sensor distinguish the difference between sodium chloride and any other number of ions in the solution that all have some influence on electrical conductivity of the soil/water/air matrix.

Application of Bulk EC Measurements

While it is difficult to make apples to apples comparisons with the bulk EC, we can identify certain benchmarks. For example, if the soil moisture reaches a threshold such as field capacity, the bulk EC can be recorded at that threshold to make a comparison. This would be useful in situations where soil salinity is a problem and monitoring is necessary.

In some circumstances, the pore water EC can be estimated from knowledge about the dielectric permittivity of the soil (Hilhorst 1999). This equation allows us to make comparable pore water EC estimates from bulk EC measurement in most soils:

sigma subscript p space equals fraction numerator epsilon subscript r p end subscript sigma subscript b over denominator epsilon subscript r b end subscript minus e subscript r b end subscript _ O end fraction

Where σp is the pore water EC, εrp is the real dielectric content of water (≈80), σb is the bulk EC measured in the soil, and εrb is the real dielectric permittivity of the soil. εrb_O is an offset, and 3.4 can be used as the offset for most inorganic soils. Note that only sensors that use the Coaxial Impedance Dielectric Reflectometry method of moisture measurement can determine the real dielectric permittivity.

Total Dissolved Solids (TDS)

The total dissolved solids (in g/L or ppm) of a water sample can be estimated from the electrical conductivity. To assess the TDS in soil you need to first obtain the pore water EC from either the equation above or from a slurry water extract. TDS calculated from EC may be less meaningful for soil pore water because there could be other constituents dissolved in the water that do not contribute to the EC of the water, such and nitrates, phosphates and other factures that exist in soil but do not occur in a water sample. Another source of error with TDS estimation from EC is the fact that different salts have different EC strengths and solubility. Calcium chloride will be under-represented in a TDS calculation because it has a lower EC value and will fall out of solution much quicker than sodium chloride (McBride 1994). Despite the challenges associated with estimating TDS from EC, the equation below can be used with a soil sensor’s EC measurements to estimate the TDS in a water or slurry extract sample.

Water Salinity (g/L) ≈ EC (S/m) x 6.4

To verify the TDS estimation from EC or perhaps correct this equation for a specific water sample, one can dry down a water sample and obtain the weight of the material left behind for a true gravimetric measurement of TDS. Note that if the EC measurement is used to estimate the TDS, the sensor’s tines need to be completely submerged in the water sample or the water extract of the slurry.

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